Sugar+sulfuric acid
One of the most spectacular chemistry demonstrations is also one of the simplest.It's the dehydration of sugar with sulfuric acid.
All you have to do to perform this demonstration is to put ordinary table sugar in a glass beaker and to add concentrated sulfuric acid. You will see that the sulfuric acid removes water from the sugar in a highly exothermic reaction which release heat, and fumes. This reaction is a dangerous one because of the toxicity of the fumes and because of the heat but the reaction smells a lot like caramel. The white sugar turns into a black carbonized tube that pushes itself out of the beaker.Try it, it's very impressive.
Explanation:
In fact, as said before, the sulfuric acid will react with sugar following these two reactions:
Sugar is dehydrated:
C12H22O11 = 12 C (graphite) + 11 H2O ( l )
Sulfuric acid is hydrated:
H2SO4 , n H2O + m H2O = H2SO4 , (n+m) H2O + heat